1 material safety data sheet material safety data sheet material safety data sheet material safety data sheet fuzhou kuncai fine chemicals co., ltd tel: +86-591-85588193 fax: +86-591-8557233 3 web site: www.fzkuncai.com e-mail:fzkc@fzkuncai .com address: haicheng road, yuanhong invest zone, fuqin g fuzhou , fujian, china. 350314 revision date: 2012/01/01 version:1.0 section 2.composition and information on ingredient s chemical name %(w/w) cas no. ci no. mica 56-64 12 001-26-2 77019 titanium oxide(tio 2 ) 17-21 13463-67-7 77891 iron(iii) oxide(fe 2 o 3 ) 21-23 1309-37-1 77491 section 3.hazards identification 3.1 classification of the substance or mixture: hazard description: not applicable information concerning particular hazards for human and environment: the product is not classified as dangerous accordin g to directive 67/548/eec,1999/45/ecandregulation(ec)no.1272/2008 classification system: the classification is according to the latest editi on of the directive 67/548/eec,1999/45/ecandregulation(ec)no.1272/2008, and extended by company and literature data. 3.2 label elements: ghs label elements : void section 1. identification of the substance/mixture and of the company 1.1product name gold luster series KC307 1.2 use: colorants for industrial use 1.3 further information obtainable from: fuzhou ku ncai fine chemicals co.,ltd. 1.4 reach reference number: 05-2114266367-41-0000(f e 2 o 3 ) reach reference number: 01-2119489379-17-0024(tio 2 ) free datasheet http://www.datasheet-pdf.com/
2 3.3 other hazards: not available potential health effects primary routes of exposure: routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. routes of entry for gases include inhalation and eye contact. skin cont act may be a route of entry for liquefied gases. irritation / corrosion: inhalation of dust may cause respiratory tract irri tation, coughing and breathing difficulties. contac t with the eyes or skin may cause mechanical irritation. chronic toxicity: carcinogenicity: may cause cancer by inhalation. contains a compound classified as iarc group 2b (possibly carcinogenic to humans). repeated dose toxicity: prolonged or repeated exposure may cause pulmonary problems. potential environmental effects aquatic toxicity: at the present state of knowledge, no negative ecol ogical effects are expected. the inhibition of the degradation activity of activated sludge is not anticipated whe n introduced to biological treatment plants in appr opriate low concentrations. the product has not been tested. th e statement has been derived from the properties of the individual components. s ection 4. first aid measures 4.1 description of first aid measures: general advice: remove contaminated clothing. if inhaled: move person to fresh air. consult doctor in event o f any complaints. if difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention. if on skin: wash with soap and water. if irritation persists, s eek medical attention. wash thoroughly with soap and water. if irritation develops, seek medical attention. if in eyes: immediately flush eyes with water for at least 15m inutes.if discomfort persists, seek medical attenti on. wash affected eyes for at least 15 minutes under ru nning water with eyelids held open. if irritation d evelops, seek medical attention. if swallowed: if large quantities are ingested, seek medical adv ice. not a hazard under normal use conditions. rinse mouth and then drink plenty of water. do not induce vomiting. never induce vomiting or give anyt hing by mouth if the victim is unconscious or having convul sions. seek medical attention if necessary. information for doctor: the following symptoms may occur: not available hazards : not available treatment : not available 4.2 most important symptoms and effects, both acute and delayed: not available 4.3 indication of any immediate medical attention a nd special treatment needed: not available s ection 5. fire fighting measures 5.1extinguishing media: not available suitable extinguishing agents: co2, powder or water spray. fight larger fires with water spray or alcohol resistant foam. 5.2special hazards arising from the substance or mi xture: not available protective equipment: no special measures required. 5.3advice for firefighters: not available free datasheet http://www.datasheet-pdf.com/
3 section 6.accidental release measures 6.1 personal precautions, protective equipment and emergency procedures: wear appropriate respiratory protection. use person al protective clothing. ensure adequate ventilation . 6.2 environmental precautions: do not allow to enter sewers/surface or ground wat er. 6.3 methods and material for containment and cleani ng up: for small amounts: pick up with suitable appliance and dispose of. for large amounts: pick up with suitable appliance and dispose of. spills should be contained and placed in suitable c ontainers for disposal. 6.4 reference to other sections: not available. section 7.handling and storage general advice: breathing must be protected when large quantities a re decanted without local exhaust ventilation. avoi d contact with the skin, eyes and clothing. keep in a cool place. keep container dry. 7.1 precautions for safe handling: avoid dust formation. closed containers should only be opened in wellventilated areas. information about fire-and explosion protection: no special measures required. 7.2 conditions for safe storage, including any inco mpatibilities: requirements to be met by storerooms and receptacle s: no special requirements information about storage in one common storage fac ility: not required. further information about storage conditions: none. incompatibilities: not available 7.3 specific end use(s): not available section 8.exposure controls personal protection 8.1 exposure controls: personal protective equipment: wear a nioshcertified (or equivalent) organic vapo ur/particulate respirator. observe osha regulations for respirator use (29 cfr 1910.134). eye protection: safety glasses with sideshields. protection of hands: the glove material has to be impermeable and resist ant to the product/the substance/the preparation. due to missing tests no recommendation to the glove material can be give for the product/the preparati on/the chemical mixture. selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. material of gloves: the selection of the suitable gloves does not only depend on the material, but also on further marks o f quality and varies from manufacturer to be manufacturer. as the product is a preparation of several substances, th e resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the applicati on. penetration time of glove material: the exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. free datasheet http://www.datasheet-pdf.com/
4 general safety and hygiene measures: handle in accordance with good industrial hygiene a nd safety practice. due to the colouring properties of the product closed work clothes should be used, to avoi d stains during manipulation. hands and/or face sho uld be washed before breaks and at the end of the shift. w ash soiled clothing immediately. primary irritant effect on the skin: no irritant effect on the eye: no irritating effect sensitization: no sensitizing effects known additional toxicological information: the products is not subject to classification acco rding to the calculation method of the general eu c lassification guidelines for preparations as issued in the latest version. when used and handled according to specifications, the product does not have any harmful effects to ou r experience and the information provided to us. toxicokinetics, metabolism and distribution: not available acute effects(acute toxicity, irritation and corros ivity) : quantitative data on the toxicity of this product i s not available. product does not contain any delet erious matter. repeated does toxicity: prolonged or repeated exposure to dust may cause pu lmonary problems. cmr effects (carcinogenity, mutagencity and toxicit y for reproduction): the results of animal experiments using pearl luste r pigment of this type indicate no toxicological re levant properties. since the substance is poorly absorbed, no systemic effects are to be anticipated. inhalation of dusts should be avoided as even inert dusts may impair respiratory organ functions. no e vidence of carcinogenic properties. no evidence of mutagenic o r teratogenic effects. section 9.physical and chemical properties 9.1 information on basic physical and chemical prop erties: form powder odor odorless color a free flowing off gold powder with a bright lust er. particle size: 1060m explosion limits lower not available upper not available oxidizing properties not available viscosity dynamic not available ph-value 7.011.0(10% aqueous suspension) boiling /condensation not available point melting /freezing point not available specific gravity approx. 2.8~3.4 g / cm 3 (water=1) ignition temperature not available self-igniting products is not selfigniting danger of explosion product does not present an explosion hazard solubility insoluble in water electric conduction nonconduction free datasheet http://www.datasheet-pdf.com/
5 impurity <0.5% chemical stability acid and alkali resistance under the normal tempera tures. section 10.stability and reactivity 10.1 reactivity: no decomposition if used according to specification s 10.2 chemical stability: acid and alkali resistance under the normal tempera tures 10.3 possibility of hazardous reactions: not available 10.4 conditions to avoid: not available 10.5 incompatible materials: not available materials t be avoided: not available dangerous reactions: no dangerous reactions known 10.6 hazardous decomposition products: not available hazardous reactions: no hazardous reactions when stored and handled acco rding to instructions. the product is chemically stable. hazardous polymerization will not occur. decomposition products: hazardous decomposition products: no hazardous deco mposition products if stored and handled as prescribed/indicated. thermal decomposition: no data available. corrosion to metals: no corrosive effect on metal. section 11.toxicological information information on toxicological effects: acute toxicity oral: type of value: ld50 species: rat value: > 2,000 mg/kg the product has not been tested. the statement has been derived from the properties of the individual components. irritation / corrosion skin: may cause mechanical irritation. eye: may cause mechanical irritation. carcinogenicity information on: titanium dioxide iarc (international agency for research on cancer) has classified this substance as group 2b (the agen t is possibly carcinogenic to humans). in longterm stud ies in rats in which the substance was given by inh alation, a carcinogenic effect was observed. tumors were only observed in rats after chronic inhalative exposure to high concentrations which caused sustained lung inflamma tion. in longterm studies in rats and mice in whic h the substance was given by feed, a carcinogenic effect was not observed. dermal exposure is not expected t o be carcinogenic. section 12. ecological information 12.1 toxicity: no ecological problems are to be expected when this product is handled and used with due care and attention. 12.2 persistence and degradability: not available 12.3bioaccumulative potential: not available 12.4 mobility in soil: not available 12.5 results of pbt and vpvb assessment: not available 12.6 other adverse effects: not available additional ecological information: free datasheet http://www.datasheet-pdf.com/
6 general notes: water hazard class 1(german regulation)(selfassess ment):slightly hazardous for water do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. fish acute: fish/lc50 (96 h): not determined chronic: no data available. aquatic invertebrates acute: daphnia/lc50 (48 h): not determined chronic: no data available. aquatic plants toxicity to aquatic plants: algae/ec50 (72 h): not determined microorganisms toxicity to microorganisms: bacteria/ec50 (0.5 h): not determined degradability / persistence biological / abiological degradation evaluation: not readily biodegradable (by oecd criteria). the colourant is insoluble in water and can thus be separated from water mechanically in suitable effluent treatment plant section 13.disposal and considerations 13.1 waste disposal of substance: must be disposed of or incinerated in accordance wi th local regulations. dispose of in a licensed facility. do not discharge into drains/surface waters/groundwater. it is the waste generator's responsibility to determine if a partic ular waste is hazardous under rcra. 13.2 container disposal: uncontaminated packaging can be reused. packs that cannot be cleaned should be disposed of in the sam e manner as the contents. section 14.transport information 14.1 land transport adr/rid (cross-border) usdot not classified as a dangerous good under transport regulations transport category: 14.2 maritime transport imdg 14.2.1 imdg class: not classified as a dangerous good under transport regulations label: - 14.2.3 packaging group: - ems number: - marine pollutant: no 14.2.4 proper shipping name: - 14.3 air transport icao-ti and iata-dgr 14.3.1 icao/iata class: not classified as a dangerous good under transport regulations 14.3.2 un/id number: - label: 14.3.3 packaging group: - 14.3.4 proper shipping name: - free datasheet http://www.datasheet-pdf.com/
7 un (model regulation): - 14.4 environmental hazards: not available 14.5 special precautions hazards: not available section 15. regulatory information 15.1 safety, health and environmental regulations/legisl ation specific for the substance or mixture: sara section 335(extremely hazardous substances): none of the ingredients is listed. section 313 (specific toxic chemical listings): none of the ingredients is listed. proposition 65 chemical known to cause cancer: none of the ingredients is listed. chemical known to cause reproductive toxicity for f emales: none of the ingredients is listed. chemical known to cause developmental toxicity: none of the ingredients is listed. cancerogenity categories epa(environmental protection agency) none of the ingredients is listed. ntp(national toxicology program) none of the ingredients is listed. osha-ca(occupational safety& health administration) none of the ingredients is listed. labelling according to eu guidelines: observe the general safety regulations when handlin g chemicals. the product has not been classified and marked in a ccordance with eu directives/respective national la ws. the product is not subject to identification regula tions under eu directives and the ordinance on haza rdous materials the product has not classified as dangerous accordi ng to directive 67/548/eec, 1999/45/ec and regulati on (ec) no.1272/2008. national regulations candidate list of substance of very high concern(sv hc) according echa (18/06/2010) none of the ingredients is listed reach regulation annex xvii restrictions list : none of the ingredients is listed reach regulation annex xvii authorization recommend ation list: none of the ingredients is listed free datasheet http://www.datasheet-pdf.com/
8 section 16.other information the contents and format of this msds are in accordi ng with regulation (ec) no.1272/2008.(ec)no.1907/20 06,eu commission directive 1999/45/ec, 67/548/eec. disclaimer of liability: the information in this msds was obtained from sour ces which we believe are reliable. however,, the in formation is provided without any warranty, express or implied, regarding its correctness. the conditions or method of handling ,storage, use or disposal of the product a re beyond our control and may be beyond our knowle dge. for this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage o r expense arising out of or in anyway connected with the handling, st orage, use or disposal of the product. this msds/sd s was prepared and is to be used only for this product. if the pro duct is used as a component in another product, thi s msds/sds information may no the applicable. relevant rphrases 36/377/38 irritating to eyes, respiratory system an d skin. abbreviations and acronyms: adr: accord enropeen sur le transport des merchandi ses dangerous par route(european agreement concerni ng the international transport of dangerous goods by rail) . imdg: international maritime code for dangerous goo ds iata: international air transport association iatadgr: dangerous goods regulations by the international air association (iata) icao: international civil aviation organization icaoti: technical instructions by the internation al civil aviation organization(icao) ghs: globally harmonized system of classification a nd labeling of chemicals. acgih: american conference of governmental industri al hygienists. lc50: lethal concentration,50 percent ld50:lethal dose,50 percent hmis iii rating health: 1 flammability: 0 physical hazard: 0 hmis use a numbering scale ranging from 0 to 4 to i ndicate the degree of hazard. a value of zero means that the substance possesses essentially no hazard; a rating of four indicates extreme danger. although similar , the two rating systems are intended for different purposes, and us e different criteria. the hmis system was designed to communicate workplace hazard information to employees who handl e hazardous chemicals. end of data sheet free datasheet http://www.datasheet-pdf.com/
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